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Bitumen

Bitumen is a highly viscous, sticky, black hydrocarbon, either refined from crude oil or found in natural deposits, primarily used as a binder in road construction (asphalt) and for waterproofing, particularly in roofing. Composed of roughly 85% carbon and 10% hydrogen, it provides excellent adhesive properties. Key health risks include skin/eye irritation and respiratory issues from hot fumes. 

What is Bitumen Made Of?

  • Properties: It is solid or semi-solid at room temperature but becomes liquid when heated, allowing it to act as a powerful, waterproof adhesive.

  • Composition: Bitumen is a complex mixture of heavy hydrocarbons, consisting mainly of Carbon ( 85%) and Hydrogen ( 10%), along with sulfur, nitrogen, oxygen, and trace metals like vanadium and nickel.

  • Source:

     It is obtained as a refined residue from the distillation of crude oil or found naturally in deposits like oil sands and pitch lakes

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Common Uses of Bitumen

  • Road Construction (Asphalt): The primary use is binding stone, sand, and gravel to create asphalt pavements for roads, highways, and airports.

  • Roofing: Used for waterproofing roofs, particularly in flat roof systems and bituminous shingles.

  • Waterproofing & Coating: Applied as a coating for pipelines, water tanks, and in the construction of foundations. 

How Bitumen is Used in Road Construction and Roofing

  • Road Construction: Known as "asphalt" in many regions, it is mixed with aggregates (sand/gravel) to create a durable, waterproof surface. It functions as the sticky binder holding the mixture together.

  • Roofing: It acts as a waterproof barrier. It is often used in asphalt shingles or in "built-up roofing" (BUR) systems, where multiple layers of bitumen and reinforcing fabrics are applied. 

Health and Safety Concerns

  • Exposure Effects: Direct contact or inhalation of fumes from hot bitumen can cause skin irritation, eye irritation, nausea, and respiratory discomfort.

  • Handling Hazards: Because it is usually applied hot, it poses a severe burn risk. Proper protective equipment (PPE) is required to prevent contact with skin and eyes. 

Note: In the US, the term "asphalt" is often used for the finished pavement mixture, while "bitumen" refers to the binder itself. 

Sulphur

Sulfur (symbol S, atomic number 16) is a bright yellow, nonmetallic, multivalent, and brittle solid at room temperature. It is essential for life, found in proteins and amino acids, and widely used in industry for creating sulfuric acid, fertilizers, and, notably, as a skin treatment to absorb excess sebum, treat acne, and aid in keratin formation. It is found in volcanic regions, fossil fuels, and various foods. 

 

Properties of Sulfur 

  • Conductivity: Poor conductor of electricity.

  • Reactivity: Reactive with all metals except gold and platinum. 

  • Symbol and Atomic Number: S, 16.

  • Physical State: Brittle, odorless, tasteless yellow solid.

  • Structure:

    Forms cyclic octatomic molecules (S8cap S sub 8 𝑆8)

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Uses of Sulfur 

  • Sulfuric Acid Production: The primary industrial use, essential for making fertilizers, chemicals, and batteries.

  • Industrial Applications: Used in rubber vulcanization, paper manufacturing, and ore processing.

  • Agricultural/Pesticide Use: Functions as a fungicide and fertilizer for crops.

  • Medicine: Used in skin-care products (soaps, lotions) to treat acne, dandruff, and dermatitis due to its antimicrobial properties. 

Health Benefits and Biological Role 

  • Amino Acid Synthesis: Necessary for producing cysteine and methionine, which are vital for protein structure.

  • Structural Support: Plays a key role in the formation of collagen and keratin (skin, hair, nails).

  • Metabolic Function: Involved in cellular signaling and detoxification of free radicals. 

 

Where Sulfur is Found 

  • Nature: Found in its elemental form, often near volcanoes.

  • Fossil Fuels: Extracted from natural gas, coal, and crude oil, where it is considered an impurity that must be removed.

  • Dietary Sources: Abundant in protein-rich foods like eggs, meat, fish, legumes, nuts, onions, and garlic. 

 

Sulfur is the 10th most abundant element in the universe, providing essential structural components for life and a critical raw material for global industrial processes. 

Diesel (EN590 10 PPM)

EN590 is the European standard for automotive diesel fuel, ensuring high-quality, low-emission performance, also known as Ultra-Low Sulfur Diesel (ULSD) with a maximum of 10 ppm sulfur. It allows up to 7% FAME biodiesel content, has a minimum cetane number of 51, and is designed for modern diesel engines. It is widely used across Europe for superior combustion efficiency. 

Key Aspects of EN590 Diesel:

  • Performance Metrics: Includes a high Cetane Number (typically >51) for improved ignition and combustion, and a flashpoint above .

  • Cold Weather Performance: The Cold Filter Plugging Point (CFPP) varies by season, designed to be lower in winter (e.g., down to  or lower) to prevent fuel gelling.

  • Usage: It is mandatory for road vehicles in the EU and widely utilized for modern diesel engines to reduce harmful emissions and ensure engine longevity.

  • Variants: Often referred to as ULSD, it also includes various grades for different climates, ensuring proper engine operation. 

  • Sulphur Content: Extremely low, at a maximum of 10 mg/kg (10 ppm), adhering to strict environmental standards.

  • Composition: It is typically a blend of petroleum-based diesel and up to 7% FAME (Fatty Acid Methyl Ester) biodiesel. .

Petroleum Coke

  • Petroleum coke (petcoke) is a carbon-rich solid byproduct of heavy oil refining, primarily used as fuel in cement kilns and power plants, or in manufacturing anodes for aluminum smelting. While offering high energy density and stability, it emits 5–10% more  than coal per unit of energy, causing significant environmental concerns. It poses respiratory risks from fine dust exposure. 

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  • Key Details About Petroleum Coke

  • Uses: It is mainly used in industrial boilers for power generation and as a raw material for anodes in the aluminum industry. It is also used in steel manufacturing and in producing titanium dioxide.

  • Health Effects: Inhaling petcoke dust, especially the fine particles, can irritate the respiratory tract, eyes, and skin. It is considered a potential respiratory irritant and poses hazards to workers handling the material due to trace heavy metals and sulfur.

  • Environmental Impact: It is a, highly carbon-intensive fuel, releasing more greenhouse gases (5% to 10% more ) than coal per unit of energy. It also contains high sulfur levels (0.2%–6%), contributing to sulfur dioxide emissions.

  • Difference from Coal: Petcoke has a higher heating value (approx. 14,308 Btu/lb) and higher carbon content (>85%) than most coal, but it also produces more pollutants. It is a residual byproduct of oil refining, whereas coal is mined.

  • Alternatives: Alternatives include natural gas, coal (which is less carbon-intensive), and renewable energy sources in industrial applications.

  • Types include green coke (unfinished) and calcined coke (further heated for industrial applications). It is extensively produced in the US, China, and India. 

Propane (C3)

Propane (/ˈproʊpeɪn/) is a three-carbon chain alkane with the molecular formula C3H8. It is a gas at standard temperature and pressure, but becomes liquid when compressed for transportation and storage. A by-product of natural gas processing and petroleum refining, it is often a constituent of liquefied petroleum gas (LPG)

Butane (C4)

  • Butane is a highly flammable, colorless, and easily liquefied gas with the molecular formula C4H10cap C sub 4 cap H sub 10 𝐶4𝐻10.

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  • It is a four-carbon saturated alkane often derived from natural gas processing and petroleum refining. Primarily used as a fuel in lighters, aerosol propellant, and in gasoline blending, it is frequently supplied as a pressurized, liquefied petroleum gas (LPG). 

  • Key Properties and Characteristics: 

  • Safety: Highly flammable, vapors are heavier than air, and it can cause frostbite on skin contact.

  • Uses: Common fuel for portable stoves, cigarette lighters, refrigerant, and feedstock for petrochemical production. 

  • Formula: C4H10 cap C sub 4 cap H sub 10 𝐶4𝐻10

  • Appearance: Colorless gas with a faint petroleum-like odor.

  • Isomers:

    Exists as n-butane (straight-chain) and isobutane (branched-chain).

  • Butane is often transported and stored under pressure as a liquid. It is a component of crude C4 streams, which are critical in the chemical industry for producing materials like butadiene. 

 
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